Fragmentations of protonated benzaldehydes via intermediate ion/molecule complexes
نویسندگان
چکیده
منابع مشابه
Remote fragmentations of protonated aromatic carbonyl compounds via internal reactions in intermediary ion-neutral complexes.
Protonated aromatic aldehydes and methyl ketones 1a-10a, carrying initially the proton at the carbonyl group, are prepared by electron impact-induced loss of a methyl radical from 1-arylethanols and 2-aryl-2-propanols, respectively. The aryl moiety of the ions corresponds to a benzene group, a naphthalene group, a phenanthrene group, a biphenyl group, and a terphenyl group. respectively, each s...
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ژورنال
عنوان ژورنال: Organic Mass Spectrometry
سال: 1986
ISSN: 0030-493X,1096-9888
DOI: 10.1002/oms.1210211012